SiO$_x$-Rich Electrode Directly Optimized Using Key Formulation Parameters - ST2E
Article Dans Une Revue Journal of The Electrochemical Society Année : 2024

SiO$_x$-Rich Electrode Directly Optimized Using Key Formulation Parameters

Résumé

The use of key parameters of the SiO$_x$/graphite electrode formulation, and their critical values, makes it possible, without any trial-and-error type experimentation, to identify optimal electrode formulations for different SiO$_x$/graphite mass ratios ranging up to 40:60. From the first attempt, electrodes presenting good cyclability at high surface capacity of 5.2 mA h cm$^{−2}$ were formulated, reaching for example more than 93% capacity retention after 60 cycles in a full cell, with an electrolyte rich in FEC and EC-free, however with a prelithiation strategy. With a positive electrode based on NMC 811 , the gains in volumetric energy and power density are + 18 and + 28% compared to graphite, considering only the electrode volumes. The principle of using the key electrode formulation parameters introduced here is expected to accelerate and facilitate the optimization of electrode formulations.

Domaines

Autre
Fichier sous embargo
Fichier sous embargo
0 1 7
Année Mois Jours
Avant la publication
vendredi 3 janvier 2025
Fichier sous embargo
vendredi 3 janvier 2025
Connectez-vous pour demander l'accès au fichier

Dates et versions

hal-04655473 , version 1 (23-08-2024)

Identifiants

Citer

Clément Meyssonnier, Cassandre Chalard, Amina Merabet, Nicolas Goubard-Bretesché, Nicolas Dupré, et al.. SiO$_x$-Rich Electrode Directly Optimized Using Key Formulation Parameters. Journal of The Electrochemical Society, 2024, 171 (7), pp.070501. ⟨10.1149/1945-7111/ad5a41⟩. ⟨hal-04655473⟩
131 Consultations
1 Téléchargements

Altmetric

Partager

More